Jens Beckmann
@jensbeckmann16
Beckmann lab @ Universität Bremen
Inorganic and organometallic chemistry of the p-block and late d-block elements
ID: 1407965902969188355
24-06-2021 07:37:06
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"Scientist Discovers New Element - Administratium" (AD). Atomic Number: 0. Inert. Its presence impedes reactions. Half-life of three years but does not actually decay, just reorganizes. h/t Thomas F Lennon
Super excited to share my Schlenk Line tutorial which is now online in Organometallics 🥳 I hope that this tutorial will be a helpful resource to anyone performing or teaching air- and moisture-sensitive techniques! #RealTimeChem #ChemEd #SchlenkLine pubs.acs.org/doi/10.1021/ac…
A stable nitrene is reported in Science Magazine. Synthesized by photolysis of an arylazide, CSD entry PORPOF, which has a triplet ground state, remains unchanged for at least 3 days when stored under an argon atmosphere. 🔗ccdc-info.com/3zp2NNE #FeaturedStructureFriday
Expanding the horizons for bismuth as a redox catalyst. Now for cyclopropanation. J. Am. Chem. Soc. pubs.acs.org/doi/epdf/10.10… with Shengyang Ni & Davide Spinnato
#Bismuth shows transition metal-like behavior, engaging in CH activation #catalysis. Now out in J. Am. Chem. Soc.: pubs.acs.org/doi/10.1021/ja…. Thanks to WangGroupPitt for taking us on this journey! University of Pittsburgh Philipps-Universität
Very excited to share our recent paper in J. Am. Chem. Soc., from the Thesis of Philip Keil 🍾 We demonstrate predictable energetic tuning of cooperative H2 activation through ligand design, with amazing kinetic studies from PK, and DFT from Tibor Szilvási 🙌 tinyurl.com/2rjfwkuk
Xufang’s work on the C-F activation of monofluorobenzene using a neutral dialumene is just out in J. Am. Chem. Soc.! Many congrats to Xufang and huge thanks to the Zhu group! pubs.acs.org/doi/10.1021/ja…
Check out Zejie's latest paper in Nature Chemistry on metal substituted carbenes with triplet ground states. Fun collaboration with the Holthausen group (Frankfurt) and Heinze_Lab nature.com/articles/s4155…
Guohai's great work together with the Kaupp group has now been published in J. Am. Chem. Soc.. A single O atom is stabilised by a MG Lewis acid to form OBeF2, showing interesting fluorine-specific interactions. Great support Humboldt-Stiftung, CRC 1349 Fluorine-Specific Interactions see pubs.acs.org/doi/10.1021/ja…
Our Perspective Article in J. Am. Chem. Soc. Thanks co-author Nilanjana Mukherjee Thanks J. Am. Chem. Soc. pubs.acs.org/doi/10.1021/ja…
Electrophilic C(sp2)-H Cyanation with Inorganic Cyanate (OCN-) by PIII/PV=O-Catalyzed Phase Transfer Activation (Alexander T. Radosevich and co-workers) MIT Chemistry #openaccess Shicheng Hu onlinelibrary.wiley.com/doi/10.1002/an…
I've always looked for a comprehensive review of d-block tetrylene/yne chemistry, but it didn't exist...until now!! 🤩 This took an entire year to put together, SUPER happy that this HUGE 96-page review is now published in Chem Soc Rev, check it out 👇 tinyurl.com/mrymtnek
“Hydridic Hydrogen-Bond Donors” Are Not Hydrogen-Bond Donors | Journal of the American Chemical Society Vrije Universiteit Amsterdam Radboud University @[email protected] UJ News #Hydridic #HBond #Donor pubs.acs.org/doi/10.1021/ja…
Today, Eric Rivard Group gave a marvellous talk at the University of Bremen. In return, we showed him the sights and did some beer tasting. Sweet life
Our manuscript on borafluorene-mediated sulfur activation is published in Inorganic Chemistry (pubs.acs.org/doi/10.1021/ac…)! Nathan Frey leads this study where he reports boryl-linked S7 and S8 catenates and related chalcogenide molecules! Gilliard Group Edwin Webster #maingroup #boron
